Publications

2024
  • 154. Ming-Yao Huang, Jia-Bao Zhao, Cheng-Da Zhang, Yuan-Jun Zhou, Zhan-Sheng Lu, Shou-Fei Zhu*. Enantioselective α-boryl carbene transformations J. Am. Chem. Soc. 2024, 146, 9871-9879.


  • 153. Peng He, Mu-Han Guan, Meng-Yang Hu, Yuan-Jun Zhou, Ming-Yao Huang, Shou-Fei Zhu*. Iron-catalyzed allylic C(sp3)-H silylation: spin-crossover-efficiency-determined chemoselectivity. Angew. Chem. Int. Ed. 2024, e202402044.


  • 152. Qiao Zhang, Xiang-Yu Liu, Yan-Dong Zhang, Ming-Yao Huang, Xin-Yu Zhang, Shou-Fei Zhu*. Iron-catalyzed C(sp3)-C(sp3) coupling to construct quaternary carbon centers. J. Am. Chem. Soc. 2024, 146, 5051-5055. (Highlighted by Org. Process Res. Dev. 2024, 28, 805-815)


  • 151. Peng He, Meng-Yang Hu, Jin-Hong Li, Tian-Zhang Qiao, Yi-Lin Lu, Shou-Fei Zhu*. Spin effect on redox acceleration and regioselectivity in Fe-catalyzed alkyne hydrosilylation. Natl. Sci. Rev.2024, 11, nwad324.


  • 150. Lu-Jie Li#, Yuli He#, Yunhui Yang#, Jun Guo#, Zhan Lu*, Congyang Wang*, Shaolin Zhu*, Shou-Fei Zhu*. Recent advances in Mn, Fe, Co, Ni-catalyzed organic reactions. CCS Chem. 2024, 6, 537-584.


2023
2022
  • 135. Ming-Yao Huang, Shou-Fei Zhu*. Catalytic reactions for enantioselective transfers of donor-substituted carbenes. Chem Catal. 2022, 2, 3112-3139.

  • 134. You Li#, Yu-Xuan Su#, Yu-Tao Zhao, Lu Liu, Mao-Lin Li, Shou-Fei Zhu*. Enantioselective synthesis of unnatural carbamate-protected α-alkyl amino esters via N-H bond insertion reactions. ACS Catal. 2022, 12, 13143-13148.

  • 133. Hui-Na Zou, Yu-Tao Zhao, Liang-Liang Yang, Ming-Yao Huang, Jing-Wei Zhang, Meng-Lin Huang, Shou-Fei Zhu*. Catalytic asymmetric synthesis of chiral propargylic boron compounds through B-H bond insertion reactions. ACS Catal. 2022, 12, 10654-10660.


  • 132. Yan-Dong Zhang, Xiao-Yu Li, Qian-Kun Mo, Wen-Bin Shi, Jia-Bao Zhao, Shou-Fei Zhu*. Highly regioselective cobalt-catalyzed hydroboration of internal alkynes. Angew. Chem. Int. Ed. 2022, 61, e202208473.



  • 131. Wen-Tao Li, Meng-Yang Hu, Jun-Wen Xiong, Xin-Yu Zhang, Shou-Fei Zhu*. Iron-catalyzed hydroalumination of internal alkynes. Chem. Sci. 2022, 13, 7873-7879.



  • 130. Ming-Yao Huang, Yu-Tao Zhao, Cheng-Da Zhang, Shou-Fei Zhu*. Highly regio-, stereo-, and enantioselective copper-catalyzed B-H bond insertion of α-silylcarbenes: efficient access to chiral allylic gem-silylboranes. Angew. Chem. Int. Ed. 2022, 61, e202203343.


  • 129. Wei Sun, Ming-Peng Li, Lu-Jie Li, Qiang Huang, Meng-Yang Hu, Shou-Fei Zhu*. Phenanthroline-imine ligands for iron-catalyzed alkene hydrosilylation. Chem. Sci. 2022, 13, 2721-2728.


     

  • 128. Qiang Huang, Wei-Na Wang, Shou-Fei Zhu*. Iron-catalyzed alkylzincation of terminal alkynes. ACS Catal. 2022, 12, 2581-2588.



  • 127. Qiang Huang, Yu-Xuan Su, Wei Sun, Meng-Yang Hu, Wei-Na Wang, Shou-Fei Zhu*. Iron-catalyzed vinylzincation of terminal alkynes. J. Am. Chem. Soc. 2022, 144, 515-526.


  • 126. Peng He, Meng-Yang Hu, Xin-Yu Zhang, Shou-Fei Zhu*. Transition-metal-catalyzed stereo- and regioselective hydrosilylation of unsymmetrical alkynes. Synthesis 2022, 54, 49-66.



2021
2020
2019
  • 106. Mao-Lin Li, Jin-Han Yu, Yi-Hao Li, Shou-Fei Zhu*, and Qi-Lin Zhou*. Highly enantioselective carbene insertion into N-H bonds of aliphatic amines. Science 2019, 366, 990-994. 




  • 105. Bo Zhou, Ying-Qi Zhang, Kai-Rui Zhang, Ming-Yang Yang, Yang-Bo Chen, You Li, Qian Peng*, Shou-Fei Zhu*, Qi-Lin Zhou, and Long-Wu Ye*. Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangementNat. Commun. 2019, 10, 3234.


  • 104. Yi-Pan Li, Shou-Fei Zhu,* and Qi-Lin Zhou.* Chiral spiro phosphoramide-catalyzed sulfa-michael addition/enantioselective protonation of exocyclic enones. Org. Lett. 2019, 21, 9391-9395.




  • 103. Qiang Huang, Meng-Yang Hu, and Shou-Fei Zhu.* Cobalt-catalyzed cyclization/hydroboration of 1,6-diynes with pinacolborane. Org. Lett. 2019, 21, 7883-7887.



  • 102. Yi-Pan Li, Zi-Qi Li, Bi-Ying Zhou, Mao-Lin Li, Xiao-Song Xue, Shou-Fei Zhu,* and Qi-Lin Zhou.* Chiral spiro phosphoric acid-catalyzed friedel-crafts conjugate addition/ enantioselective protonation reactions. ACS Catal. 2019, 9, 6522-6529. (Highlighted by Synfacts, 201915, 1049.)


  • 101. Ming-Yao Huang, Ji-Min Yang, Yu-Tao Zhao, and Shou-Fei Zhu.* Rhodium-catalyzed Si-H bond insertion reactions using functionalized alkynes as carbene precursors. ACS Catal. 2019, 9, 5353-5357. (Ming-Yao Huang and Ji-Min Yang contributed equally)


  • 100. Wen Che, Yu-Zhen Li, Jin-Chi Liu, Shou-Fei Zhu, Jian-Hua Xie, and Qi-Lin Zhou.* Stereodiverse iterative synthesis of 1,3-polyol arrays through asymmetric catalytic hydrogenation. formal total synthesis of (−)-cyanolide A. Org. Lett. 2019, 21, 2369-2373.



  • 99. Wen Che, Danyang C. Wen, Shou-Fei Zhu, and Qi-Lin Zhou.* Enantioselective total synthesis of (−)-doliculide using catalytic asymmetric hydrogenations. Helv. Chim. Acta 2019, 102, e1900023.




  • 98. Meng-Yang Hu, Jie Lian, Wei Sun, Tian-Zhang Qiao, and Shou-Fei Zhu.* Iron-catalyzed dihydrosilylation of alkynes: efficient access to geminal bis(silanes). J. Am. Chem. Soc. 2019, 141, 4579-4583.




  • 97. Min-Jie Zhou, Shou-Fei Zhu, and Qi-Lin Zhou.* Iodine-catalyzed oxidative rearrangement of amines to α-amino acetals and α-amino aldehydes. Adv. Synth. Catal. 2019, 361, 1289-1294.




2018
  • 96. Mao-Lin Li, Meng-Qing Chen, Bin Xu, Shou-Fei Zhu*, and Qi-Lin Zhou*. Enantioselective O-H bond iInsertion of α-diazoketones with alcohols cooperatively catalyzed by achiral dirhodium complexes and chiral spiro phosphoric acids. Acta Chim. Sinica. 2018, 76, 883-889. (Mao-Lin Li and Meng-Qing Chen contributed equally)


  • 95. Yue Pang, Qiao He, Zi-Qi Li, Ji-Min Yang, Jin-Han Yu, Shou-Fei Zhu*, Qi-Lin Zhou. Rhodium-catalyzed B-H bond insertion reactions of unstabilized diazo compounds generated in situ from tosylhydrazones. J. Am. Chem. Soc. 2018, 140, 10663-10668. (Highlighted by https://www.organic-chemistry.org/abstracts/lit6/464.shtm)


  • 94. Ji-Min Yang, Yu-Tao Zhao, Zi-Qi Li, Xue-Song Gu, Shou-Fei Zhu*, Qi-Lin Zhou*. Gold-catalyzed oxidative coupling of terminal alkynes and borane adducts: efficient synthesis of α-boryl ketones. ACS Catal. 2018, 8, 7351-7355.



  • 93. Yuan-Yuan Ren, Mo Chen, Ke Li, Shou-Fei Zhu*. Gold-catalyzed formal C-C Bond insertion reaction of 2-aryl-2-diazoesters with 1,3-diketones. Chem. Asian J. 2018, 13, 2606-2610.




  • 92. Ke Li, Mao-Lin Li, Qi Zhang, Shou-Fei Zhu*, Qi-Lin Zhou*. Highly enantioselective nickel-catalyzed intramolecular hydroalkenylation of N- and O-tethered 1,6-dienes to form six-membered heterocycles. J. Am. Chem. Soc. 2018, 140, 7458-7461. (Highlighted by Synfacts, 2018, 14, 0821.)



  • 91. Wen Che, Danyang C. Wen, Shou-Fei Zhu*, Qi-Lin Zhou*. Iterative synthesis of polydeoxypropionates based on iridium-catalyzed asymmetric hydrogenation of α-substituted acrylic acid. Org. Lett. 2018, 20, 3305-3309.




  • 90. Yi-Pan Li, Zi-Qi Li, Shou-Fei Zhu*. Recent advances in transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes. Tetrahedron Lett. 2018, 59, 2307-2316. 


  • 89. Yuan-Yuan Ren, Shou-Fei Zhu*, Qi-Lin Zhou*. Chiral proton-transfer shuttle catalysts for carbene insertion reactions. Org. Biomol. Chem. 2018, 16, 3087-3094. (Review)



  • 88. Meng-Yang Hu, Qiao He, Song-Jie Fan, Zi-Chen Wang, Luo-Yan Liu, Yi-Jiang Mu, Qian Peng*, Shou-Fei Zhu*. Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation. Nat. Commun. 2018, 9, 221-231.




2017
  • 87. Guo-Peng Wang, Meng-Qing Chen, Shou-Fei Zhu*, Qi-Lin Zhou*. Enantioselective Nazarov cyclization of indole enones cooperatively catalyzed by Lewis acids and chiral Brønsted acids. Chem. Sci. 2017, 8, 7197-7202.



  • 86. Ji-Min Yang, Zi-Qi Li, Shou-Fei Zhu*. Progresses on the application of stable borane adducts in the synthesis of organoborons. Chin. J. Org. Chem. 2017, 37, 2481-2497.




  • 85. Min-Jie Zhou, Shou-Fei Zhu and Qi-Lin Zhou*. Copper-catalyzed mannich-type oxidative β-functionalization of tertiary amines. Chem. Commun. 2017, 53, 8770-8773.



  • 84. Huan Xu, Yi-Pan Li, Yan Cai, Guo-Peng Wang, Shou-Fei Zhu*, Qi-Lin Zhou*. Highly enantioselective copper- and iron-catalyzed intramolecular cyclopropanation of indoles. J. Am. Chem. Soc. 2017, 139, 7697-7700. (Huan Xu, Yi-Pan Li and Yan Cai contributed equally)


  • 83. Shou-Fei Zhu*, Qi-Lin Zhou*. Iridium-catalyzed asymmetric hydrogenation of unsaturated carboxylic acids. Acc. Chem. Res. 2017, 50, 988-1001.



  • 82. Qing-Qing Cheng, Ji-Min Yang, Huan Xu, Shou-Fei Zhu*. Iron-catalyzed carbenoid insertion into C(sp3)-H bonds. Synlett. 2017, 28, 1327-1330.



  • 81. Ji-Min Yang, Zi-Qi Li, Mao-Lin Li, Qiao He, Shou-Fei Zhu*, Qi-Lin Zhou*. Catalytic B-H bond insertion reactions using alkynes as carbene precursors. J. Am. Chem. Soc. 2017, 139, 3784-3789.



  • 80. Mao-Lin Li, Shuang Yang, Xun-Cheng Su, Hui-Ling Wu, Liang-Liang Yang, Shou-Fei Zhu*, Qi-Lin Zhou*. Mechanism studies of Ir-catalyzed asymmetric hydrogenation of unsaturated carboxylic acids. J. Am. Chem. Soc. 2017, 139, 541-547. (Mao-Lin Li and Shuang Yang contributed equally to this work)



  • 79. Shuang Yang, Wen Che, Hui-Ling Wu, Shou-Fei Zhu*, Qi-Lin Zhou*. Neutral iridium catalysts with chiral phosphine-carboxy ligands for asymmetric hydrogenation of unsaturated carboxylic acids. Chem. Sci. 2017, 8, 1977-1980.



2016
  • 78. Xiao-Guang Song, Yuan-Yuan Ren, Shou-Fei Zhu*, Qi-Lin Zhou*. Enantioselective copper-catalyzed intramolecular N-H bond insertion: Synthesis of chiral 2-carboxy tetrahydroquinolines. Adv. Synth. Catal. 2016, 358, 2366-2370.



  • 77. Ming-Lei Yuan, Jian-Hua Xie, Shou-Fei Zhu, Qi-Lin Zhou*. Deoxygenative hydrogenation of amides catalyzed by a well-defined iridium pincer complex. ACS. Catal. 2016, 6, 3665-3669.



  • 76. Yan-Bo Yu, Lei Cheng, Yi-Pan Li, Yue Fu, Shou-Fei Zhu*, Qi-Lin Zhou*. Enantioselective iridium-catalyzed hydrogenation of β,β-disubstituted nitroalkenes. Chem. Commun. 2016, 52, 4812-4815.


  • 75. Hong-Lei Liu, Yang Liu, Chun-Hao Yuan, Guo-Peng Wang, Shou-Fei Zhu, Yang Wu, Bo Wang, Zhan-Hu Sun, Yu-Mei Xiao, Qi-Lin Zhou*, Hong-Chao Guo*. Enantioselective synthesis of spirobarbiturate-cyclohexenes through phosphine-catalyzed asymmetric [4+2] annulation of barbiturate-derived alkenes with allenoates. Org. Lett. 2016, 18, 1302-1305.



  • 74. Ji-Min Yang, Yan Cai, Shou-Fei Zhu*, Qi-Lin Zhou. Iron-catalyzed arylation of α-aryl-α-diazoesters. Org. Biomol. Chem. 2016. 14, 5516-5519.



  • 73. Jun-Xia Guo, Ting Zhou, Bin Xu, Shou-Fei Zhu*, Qi-Lin Zhou. Enantioselective synthesis of α-alkenyl α-amino acids via N-H insertion reactions. Chem. Sci. 2016, 7, 1104-1108.





2015
  • 72. Bin Xu, Mao-Lin Li, Xiao-Dong Zuo, Shou-Fei Zhu*, and Qi-Lin Zhou. Catalytic asymmetric arylation of α-aryl-α-diazoacetates with aniline derivatives. J. Am. Chem. Soc. 2015, 137, 8700-8703.




  • 71. Cui Guo, Dong-Wei Sun, Shuang Yang, Shen-Jie Mao, Xiao-Hua Xu*, Shou-Fei Zhu*, and Qi-Lin Zhou*. Iridium-catalyzed asymmetric hydrogenation of 2-pyridyl cyclic imines: a highly enantioselective approach to nicotine derivatives. J. Am. Chem. Soc. 2015, 137, 90-93.



  • 70. Paula Mayorga Burrezo, Xiao-Zhang Zhu, Shou-Fei Zhu, Qi-Fan Yan, Juan T. López Navarrete*, Hayato Tsuji*, Eiichi Nakamura*, Juan Casado*. Planarization, fusion, and strain of carbon-bridged phenylenevinylene oligomers enhance π-electron and charge conjugation: a dissectional vibrational raman study. J. Am. Chem. Soc. 2015, 137, 3834-3843.


  • 69. De Wang, Guo-Peng Wang, Yao-Liang Sun, Shou-Fei Zhu, Yin Wei, Qi-Lin Zhou*, Min Shi*. Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones. Chem. Sci. 2015, 6, 7319-7325.



    Graphical abstract: Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones


  • 68. Na Guo, Meng-Yang Hu, Ye Feng, Shou-Fei Zhu*. Highly efficient and practical hydrogenation of olefins catalyzed by in situ generated iron complex catalysts. Org. Chem. Front. 2015, 2, 692-696.




  • 67. Qing-Qing Cheng, Huan Xu, Shou-Fei Zhu*, Qi-Lin Zhou. Enantioselective copper-catalyzed B-H bond insertion reaction of α-diazoketones. Acta Chim. Sinica. 2015, 73, 326-329.


  • 66. Na Guo, Shou-Fei Zhu*. Iron-catalyzed hydrogenation reactions. Chin. J. Org. Chem. 2015, 35, 1383-1398.



2014
  • 65. Xiao-Hui Yang, Ke Wang, Shou-Fei Zhu, Jian-Hua Xie*, and Qi-Lin Zhou*. Remote ester group leads to efficient kinetic resolution of racemic aliphatic alcohols via asymmetric hydrogenationJ. Am. Chem. Soc. 2014, 136, 17426-17429.




  • 64. Jun-Jie Shen, Shou-Fei Zhu*, Yan Cai, Huan Xu, Xiu-Lan Xie, and Qi-Lin Zhou. Enantioselective iron-catalyzed intramolecular cyclopropanation reactions. Angew. Chem. Int. Ed. 2014, 53,13188-13191. (Highlighted by Synfacts 2014, 10, 1284).


  • 63. Bin Xu, Shou-Fei Zhu*, Xiao-Dong Zuo, Zhi-Chao Zhang, Qi-Lin Zhou*. Enantioselective N-H insertion reaction of α-aryl α-diazoketones: an efficient route to chiral α-aminoketones. Angew. Chem. Int. Ed. 2014, 53, 3913-3916.


  • 62. Xiu-Lan Xie, Shou-Fei Zhu*, Jun-Xia Guo, Yan Cai, Qi-Lin Zhou*. Enantioselective palladium-catalyzed insertion of α-aryl-α-diazoacetates into the O-H bonds of phenols. Angew. Chem. Int. Ed. 2014, 53, 2978-2981.




  • 61. Bin Xu, Shou-Fei Zhu*, Zhi-Chao Zhang, Zhi-Xiang Yu*, Yi Ma, Qi-Lin Zhou*. Highly enantioselective S-H bond insertion cooperatively catalyzed by dirhodium complexes and chiral spiro phosphoric acids. Chem. Sci. 2014, 5, 1442-1448.




  • 60. Shuang Yang, Shou-Fei Zhu, Na Guo, Song Song and Qi-Lin Zhou*. Carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins: highly enantioselective and chemoselective access to a chiral benzylmethyl center. Org. Biomol. Chem. 2014, 12, 2049-2052.




  • 59. Ze-Yu Li, Song Song, Shou-Fei Zhu*, Na Guo, Li-Xin Wang, and Qi-Lin Zhou*. Synthesis of chiral α-benzyl-β2-hydroxy carboxylic acids through iridium-catalyzed asymmetric hydrogenation of α-oxymethylcinnamic acids. Chin. J. Chem. 2014, 32, 783-787.



  • 58. Shou-Fei Zhu*, and Qi-Lin Zhou*. Iron-catalyzed transformations of diazo compounds. National Science Review. 2014, 1, 580-603.




2013
  • 57. Qing-Qing Cheng, Shou-Fei Zhu*, Yong-Zhen Zhang, Xiu-Lan Xie, and Qi-Lin Zhou*. Copper-catalyzed B-H bond insertion reaction: a highly efficient and enantioselective C-B bond-forming reaction with amine-borane and phosphine-borane adducts. J. Am. Chem. Soc. 2013,135, 14094-14097.




  • 56. Song Song, Shou-Fei Zhu, Liu-Yang Pu, Qi-Lin Zhou*. Iridium-Catalyzed enantioselective hydrogenation of unsaturated heterocyclic acidsAngew. Chem. Int. Ed.2013, 52, 6072-6075.


  • 55. Xiao-Guang Song, Shou-Fei Zhu, Xiu-Lan Xie, and Qi-Lin Zhou*. Enantioselective Copper-Catalyzed intramolecular phenolic O-H bond insertion:  synthesis of chiral 2-carboxy dihydro-benzofurans, dihydrobenzopyrans and tetrahydrobenzooxepines*. Angew. Chem. Int. Ed.2013, 52, 2555-2558.




  • 54. Song Song, Shou-Fei Zhu, Yan-Bo Yu, Qi-Lin Zhou*. Carboxy-Directed asymmetric hydrogenation of 1,1-diarylethenes and 1,1-dialkylethenes. Angew. Chem. Int. Ed.2013, 52, 1556-1559.




  • 53. Song Song, Shou-Fei Zhu, Yu Li, and Qi-Lin Zhou*. Iridium-Catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids with tetrasubstituted olefinsOrg. Lett. 2013, 15, 3722-3725




  • 52. Kang-Lun Huang, Cui Guo, Li-Jie Cheng, Long-Guan Xie, Qi-Lin Zhou, Xiao-Hua Xu*, Shou-Fei Zhu*. Enantioselective Palladium-Catalyzed ring-opening reaction of azabenzonorbornadienes with methyl 2-iodobenzoate: an efficient access to cis-dihydro benzo[c]phenanthridinones. Adv. Synth. Catal.2013, 355, 2833-2838.

    image


  • 51. Gang Li, Jian-Hua Xie*, Jing Hou, Shou-Fei Zhu, Qi-Lin Zhou*. Catalytic asymmetric hydrogenation of α-Arylcyclohexanones and total synthesis of (−)-α-LycoraneAdv. Synth. Catal. 2013, 355, 1597-1604.




  • 50. Bo Zhang, Shou-Fei Zhu*, and Qi-Lin Zhou*. Copper-catalyzed benzylic oxidation of C(sp3)-H bonds. Tetrahedron. 2013, 69, 2033-2037.



  • 49. Bo Zhang, Shou-Fei Zhu*, Qi-Lin Zhou*. Copper-Catalyzed enantioselective allylic oxidation of acyclic olefinsTetrahedron Lett. 2013, 54, 2665-2668.



2012
  • 48. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-substituted acrylic acids catalyzed by Iridium complexes with chiral spiro aminophosphine ligands. Angew. Chem. Int. Ed. 2012, 51, 8872-8875.



  • 47. Shou-Fei Zhu, Qi-Lin Zhou*. Transition-Metal-Catalyzed enantioselective heteroatom–hydrogen bond insertion reactions. Acc. Chem. Res. 2012, 45, 1365-1377.


  • 46. Jian-Hua Xie*, Shou-Fei Zhu and Qi-Lin Zhou*. Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enaminesChem. Soc. Rev. 2012, 41, 4126-4139.



  • 45. Song Song, Shou-Fei Zhu, Shuang Yang, Shen Li, Qi-Lin Zhou*. Enantioselective iridium-catalyzed hydrogenation of β,γ-unsaturated carboxylic acids: an efficient approach to chiral 4-alkyl-4-aryl butanoic acids. Angew. Chem. Int. Ed. 2012, 51, 2708-2711.



  • 44. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, Qi-Lin Zhou*. Well-defined binuclear chiral spiro copper catalysts for enantioselective N-H insertion. J. Am. Chem. Soc. 2012, 134, 436-442.



  • 43. Shou-Fei Zhu, Tao Liu, Shuang Yang, Song Song, Qi-Lin Zhou*. Enantioselective hydrogenation of (Z)- and (E)-β-arylenamides catalyzed by rhodium complexes of monodentate chiral spiro phosphorous ligands: a new access to chiral β-arylisopropylamines. Tetrahedron 2012, 68, 7685-7690.



  • 42. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*. Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol. Tetrahedron 2012, 68, 5172-5178.



2011
  • 41. Yan Cai, Shou-Fei Zhu, Guo-Peng Wang, Qi-Lin Zhou*. Iron-catalyzed C-H functionalization of indoles. Adv. Synth. Catal. 2011, 353, 2939-2944.




  • 40. Shou-Fei Zhu, Wang-Qiao Chen, Qian-Qian Zhang, Hong-Xiang Mao, Qi-Lin Zhou*. Enantioselective copper-catalyzed O-H insertion of α-diazo phosphonates. Synlett 2011, 7, 919-922.



  • 39. Bin Xu, Shou-Fei Zhu,* Xiu-Lan Xie, Jun-Jie Shen, Qi-Lin Zhou*. Asymmetric N-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids. Angew. Chem. Int. Ed. 2011, 50, 11483-11486.



  • 38. Qiu-Shi Wang, Jian-Hua Xie, Wei Li, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*. Ruthenium-catalyzed hydrovinylation of N-acetylenamines leading to amines with a quaternary carbon center. Org. Lett. 2011, 13, 3388-3391.



  • 37. Shou-Fei Zhu, Xiang-Chen Qiao, Yong-Zhen Zhang, Li-Xin Wang, Qi-Lin Zhou*. Highly enantioselective palladium-catalyzed umpolung allylation of aldehydes. Chem. Sci. 2011, 2, 1135-1140.



  • 36. Jian-Hua Xie, Shou-Fei Zhu, Qi-Lin Zhou*. Transition metal-catalyzed enantioselective hydrogenation of enamines and imine. Chem. Rev. 2011, 111, 1713-1760.

2010及以前
  • 35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.


  • 34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.


  • 33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.



  • 32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.


  • 31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.


  • 30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.



  • 29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.


  • 28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.


  • 27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.


  • 26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.


  • 25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.


  • 24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.


  • 23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.


  • 22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

    Graphical abstract: Modular chiral dendritic monodentate phosphoramidite ligands for Rh(ii)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity


  • 21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.


  • 20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.



  • 19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.


  • 18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.


  • 17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.


  • 16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.


  • 15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

    Graphical abstract: Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio


  • 14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.


  • 13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.


  • 12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.


  • 11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.


  • 10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.


  • 9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.


  • 8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.


  • 7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.


  • 6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.


  • 5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.


  • 4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.


  • 3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.


  • 2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.




  • 1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.