35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.

8. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*. Asymmetric aldol reactions catalyzed by new spiro diamine derivatives. Tetrahedron: Asymmetry 2006, 17, 384-387.

7. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Βin Liu, Qi-Lin Zhou*. Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Org. Lett. 2005, 7, 2333-2335.

6. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai -Guo Hu, Qi-Lin Zhou*. New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations. Pure Appl. Chem. 2005, 77, 2121-2132.

5. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*. Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. J. Org. Chem. 2004, 69, 4648-4655.

4. Jian-Hua Xie, Li-Xin Wang, Shuo-Fei Zhu, Yu Fu, Bao-Min Fan, Hai-Feng Duan Qi-Lin Zhou*. Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones. J. Am. Chem. Soc. 2003, 125, 4404-4405.

3. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Βin Liu, Liang Xing, Qi-Lin Zhou*. Synthesis of chiral 4,4′-disubstituted 1,1′-spirobiindane-7,7′-diols and related phosphoramidites. The substituent effect of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation. Tetrahedron: Asymmetry 2003, 14, 3219- 3224.

2. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*. Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands. Tetrahedron: Asymmetry 2003, 14, 3867- 3872.

1. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*. Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride. Tetrahedron: Asymmetry 2002, 13, 1363-1366.

35. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *. Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers. J. Am. Chem. Soc. 2010, 132,16374-16376.

34. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*. Enantioselective nickel-catalyzed reductive coupling of alkynes and imines. J. Am. Chem. Soc. 2010, 132, 10955-10957.

33. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*. Enantioselective iron-catalyzed O-H bond insertions. Nature Chem. 2010, 2, 546-551.

32. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*. Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes. J. Am. Chem. Soc. 2010, 132, 1172-1179.

31. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*. Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity. Adv. Synth. Catal. 2010, 352, 1914-1919.

30. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*. Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols. Tetrahedron: Asymmetry 2010, 21, 1216-1220.

29. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center. Sci. China Chem. 2010, 53, 1899-1906.

28. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*. From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins. Tetrahedron: Asymmetry 2009, 20, 1254-1261.

27. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*. Copper-catalyzed enantioselective carbenoid insertion into S-H bonds. Chem. Commun. 2009, 5362-5364.

26. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*. Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins. J. Am. Chem. Soc. 2008, 130, 14052-14053.

25. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*. Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids. J. Am. Chem. Soc. 2008, 130, 8584-8585.

24. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si-H Βonds. Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

23. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*. Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O-H insertion reaction. Angew. Chem. Int. Ed. 2008, 47, 932-934.

22. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, Qi-Lin Zhou*. Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity. Chem. Commun. 2008, 6048-6050.

21. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*. Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes. Adv. Synth. Catal. 2008, 350, 1507-1510.

20. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*. Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents. Chem. Asian J. 2008, 3, 2105-2111.

19. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into O-H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters. J. Am. Chem. Soc. 2007, 129, 12616-12617.

18. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*. Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. J. Am. Chem. Soc. 2007, 129, 5834-5835.

17. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*. Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols. J. Am. Chem. Soc. 2007, 129, 2248- 2249.

16. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*. Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons. Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

15. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*. Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chem. Commun. 2007, 613-615.

14. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*. Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters. J. Am. Chem. Soc. 2006, 128, 2780-2781.

13. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*. Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure. J. Am. Chem. Soc. 2006, 128, 12886-12891.

12. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*. Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes. J. Org. Chem. 2006, 71, 75-80.

11. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*. Α general synthetic route to chiral dihydroxy-9,9'-spirobifluorenes. Tetrahedron 2006, 62, 8077-8082.

10. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi -Lin Zhou*. Preparation and application of bisoxazoline ligands with α chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation. Tetrahedron: Asymmetry 2006, 17, 634-641.

9. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*. Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition. Tetrahedron: Asymmetry 2006, 17, 2761-2767.